To be certain, you'll want to consult a repair manual specific to your 1999 Chevy Malibu 3.1L V6. A Haynes or Chilton manual would be a great resource with diagrams. You can also often find diagrams online through sites like AutoZone or similar parts retailers by entering your vehicle's information. Looking at pictures of 3.1L V6 engines for that year will also help you visually identify it once you're looking under the hood.
Be careful when working near the engine. Allow the engine to cool completely before attempting to locate the valve.