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Where do you add R12 refrigerant to a 2006 Chevrolet Malibu?

You don't add R-12 refrigerant to a 2006 Chevrolet Malibu. R-12 is an older refrigerant that's been phased out due to its ozone-depleting properties. Your 2006 Malibu almost certainly uses R-134a.

Adding refrigerant to a car's AC system is a job best left to a qualified mechanic. Improperly adding refrigerant can damage the system and be dangerous. If your Malibu's AC isn't working properly, you should take it to a professional for diagnosis and repair. They will properly identify the refrigerant type and address the underlying problem, rather than just adding refrigerant which might mask a larger issue.