It's a relatively small, black box with numerous connectors. Look for a large, rectangular box with wiring harnesses connected to it. It might have a sticker identifying it as the PCM (Powertrain Control Module) – PCM and ECU are often used interchangeably.
Because of the variations, searching for "1994 Ford E150 PCM location" with images on Google Images could be helpful in visually identifying it. Using your specific engine size (e.g., 4.9L, 5.0L, 5.8L, 7.5L) in your search will further refine your results.