Because of the variations, you'll need a repair manual or a diagram specifically for your 1991 Cadillac DeVille 4.9L engine to pinpoint its exact location. Searching online for "1991 Cadillac DeVille 4.9L engine diagram" or "1991 Cadillac DeVille 4.9L EGR valve location" with images might help you locate it visually. A Haynes or Chilton repair manual is also a great investment for this type of work.
Don't rely solely on general descriptions. Visual confirmation is crucial for accurate identification.