To find it definitively:
* Consult your owner's manual: This is the best resource. It should have a diagram showing the location of all service ports, including the AC recharge port.
* Use a shop manual or online repair guides: These often have detailed diagrams of the engine bay. Search for "1999 Chevy Blazer AC recharge port location" along with your specific engine size (e.g., 4.3L V6) for better results.
* Look for a low-side service port: As mentioned, it will be a Schrader valve often capped, usually near the AC compressor and lines.
Caution: Working with refrigerant requires specialized tools and knowledge. Improper handling of refrigerant can be dangerous. If you're not experienced with AC system service, it's best to have a qualified mechanic recharge your AC system.