To relieve fuel pressure, you would typically:
* Disconnect the fuel pump relay: This is the safest and most common method. This cuts power to the pump, allowing the pressure to bleed off naturally. Consult your owner's manual or a repair manual for the location of the fuel pump relay.
* (Less Recommended) Carefully disconnect a fuel line at the fuel rail: This is risky and should only be done by someone experienced with fuel systems, as fuel will spray out. Always have a rag and safety glasses ready. This is not recommended for the average person.
In short: There's no single "pressure release valve" to find. The process is to remove the power to the fuel pump to relieve pressure.