There might be an inertia switch (also sometimes called a crash switch), which cuts fuel flow in a collision to prevent fires. This is usually located under the dash, sometimes near the driver's side kick panel or under the carpet. It's often a small, square or rectangular box. However, this is a safety device, not a readily usable shut-off switch.
If you need to completely stop fuel flow for maintenance or other reasons, you'd have to disconnect the fuel pump relay or the fuel pump's electrical connection. This requires working under the hood and disconnecting electrical components, and is potentially hazardous due to fuel system pressure. Exercise extreme caution and refer to your owner's manual before doing so.