To be certain, you should:
* Consult a repair manual specific to your 1991 Grand Prix's engine. This is the most reliable way to find the exact location. A Haynes or Chilton manual would be helpful.
* Look at diagrams online: Search for "[Your Grand Prix's engine] knock sensor location" on sites like Google Images or a parts website like AutoZone or RockAuto. Their diagrams can help you visually pinpoint it.
Remember to be cautious when working around the engine; it may still be hot. Always disconnect the negative battery terminal before starting any work.