Before attempting to charge your AC yourself:
* Consult your owner's manual: It's the best source for the precise location and instructions.
* Be aware of the risks: Improper AC charging can be dangerous. Refrigerant is under high pressure and can cause serious injury. If you're not comfortable with this task, it's best to take your vehicle to a qualified mechanic.
The high-pressure port (usually red) is generally not used for charging. Only use the low-pressure port.
If you can't find it in the described area, look closely at all components near the radiator and condenser. You might also want to do a search online for "2000 Chevrolet Impala AC charging port location" along with images to see if you can visually identify it.