To be certain, it's best to:
1. Consult your owner's manual: This is the most reliable source.
2. Check online forums: Search for "1991 Chevy S10 Blazer ECM location" on forums dedicated to GM trucks. You might find photos to help you identify it.
3. Look for a large, rectangular black box with many wire connectors: While not foolproof, this is a good visual clue.
Remember to disconnect the negative battery cable before working near any electrical components to avoid accidental short circuits.