To be certain, you should:
1. Consult a repair manual: A Haynes or Chilton manual specific to your 1997 Chevy S-10 4-cylinder will show you a diagram and the precise location. This is the most reliable method.
2. Look on the valve cover: The PCV valve is usually a small, plastic or metal valve with a hose connected to it. It might be easily visible, or it might be tucked away somewhat, but it's always in the vicinity of the valve cover.
3. Trace the hose: If you can locate a hose going from the valve cover to the intake manifold (or a similar location on the engine), follow that hose; it should lead to the PCV valve.
Without knowing the exact engine code, providing a more precise location is impossible. Using a repair manual is strongly recommended for accurate identification.