To be certain, you'll need to consult a repair manual specific to your 1999 Buick Regal's engine. A Haynes or Chilton manual will have diagrams and detailed instructions. You can also often find diagrams online through a search for "[Your Engine Size] Buick Regal PCV valve location".
However, generally, look for a small, usually plastic, valve with a single hose attached on the valve cover area. It might be capped or have a hose connecting to the intake manifold. It's often a fairly easily accessible component.