To locate it, you'll probably need to:
* Consult a 1966 Ford F100 repair manual: This is your best bet for precise location and diagrams.
* Look for the heater hoses: Follow the heater hoses entering and leaving the firewall; the valve is usually found nearby.
* Carefully examine the area under the dash: You'll likely need to remove some trim panels and possibly the glove box to access it fully.
Be prepared for some disassembly and potentially tricky maneuvering. Be sure to label and photograph components as you remove them to help with reassembly.