* Head Gasket Failure: This is a serious possibility. A blown head gasket allows combustion gases to enter the cooling system, increasing pressure and causing the coolant to overheat and boil over. This is often accompanied by white smoke from the exhaust, milky oil, or a loss of coolant that isn't evident as a leak.
* Faulty Pressure Cap: The radiator cap regulates pressure within the cooling system. A faulty cap might not be releasing pressure properly, causing excessive buildup that leads to boiling over once the engine's heat is no longer actively being removed by the cooling fan.
* Cooling System Leaks: Small leaks might not be immediately obvious while the engine is running, but as the system cools and pressure drops, they can draw in air, leading to a vacuum effect that pulls coolant back into the system, resulting in overflow.
* Faulty Water Pump: A failing water pump might not circulate coolant efficiently. When the engine stops and the pump stops, the heat in the engine block can't be dissipated quickly enough, leading to boiling over.
* Thermostat Issues: A stuck closed thermostat prevents coolant from circulating properly, leading to overheating. A stuck open thermostat might not allow the engine to reach optimal operating temperature efficiently, but isn't the most likely cause of boil-over after shut-off.
* Radiator Issues: A clogged radiator or a radiator with internal damage will impede coolant flow, leading to overheating.
* Low Coolant Level: This is a basic check, but if you're consistently low on coolant, you likely have a leak somewhere in the system.
What to do:
1. Safety First: Do not open the radiator cap when the engine is hot or even warm. The pressure inside can cause serious burns.
2. Check Coolant Level: Make sure your coolant level is sufficient and within the proper range. Top it off if necessary, but be prepared to have to add more frequently if there's a leak.
3. Inspect for Leaks: Carefully examine all hoses, clamps, the radiator, and the water pump for any visible leaks. Look for signs of coolant staining or corrosion.
4. Test the Pressure Cap: There are pressure testers available at auto parts stores that can check if your radiator cap is holding the correct pressure.
5. Check the Exhaust for White Smoke: White smoke could indicate a blown head gasket.
6. Check your Oil: Milky or foamy oil can also point to a blown head gasket.
If you're not comfortable performing these checks yourself, take your car to a mechanic. A blown head gasket is a serious repair, and early diagnosis and treatment are crucial. Ignoring the problem could cause significant engine damage.