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What causes a 95 Cadillac STS to overheat the thermostat has been replaced and it only runs hot at high speed?

Several factors could cause a 1995 Cadillac STS to overheat at high speeds, even after replacing the thermostat. Here are some potential causes to consider:

1. Faulty Radiator Cap: A faulty or damaged radiator cap can affect the cooling system's ability to maintain the correct pressure. A defective cap may not seal properly, allowing coolant to escape and leading to overheating.

2. Coolant Level: Verify the coolant level in the reservoir. Low coolant levels can cause the engine to overheat, especially at higher speeds when the engine generates more heat. Make sure the coolant level is between the "FULL" and "ADD" marks.

3. Water Pump Failure: A failing water pump may not circulate coolant efficiently throughout the engine, resulting in overheating. Check for signs of leakage or damage around the water pump.

4. Fan Clutch or Fan Motor Issues: The fan clutch or fan motor may not be working correctly. The fan helps to dissipate heat from the radiator. A faulty fan clutch or motor can cause the engine to overheat, particularly at high speeds when more airflow is needed.

5. Clogged Radiator or Hoses: A clogged radiator or radiator hoses can restrict the flow of coolant, causing the engine to overheat. Inspect the radiator and hoses for any signs of blockage, damage, or leaks.

6. Faulty Temperature Sensor: A faulty temperature sensor may provide incorrect readings to the engine's computer, causing the cooling fan not to activate at the appropriate time. This can result in overheating.

7. Head Gasket Issues: In severe cases, a blown head gasket can lead to overheating. A compromised head gasket can leak coolant into the combustion chambers, causing a loss of coolant and overheating.

8. Defective Thermostat: While you mentioned the thermostat has been replaced, there's a possibility the new thermostat is faulty or is not installed correctly. It may be worth double-checking the installation and testing the new thermostat.

To accurately diagnose the root cause of the overheating issue, it is recommended to have the vehicle inspected by a qualified mechanic. They can perform diagnostic tests and identify the specific component that is causing the problem.