To be certain, I strongly recommend:
* Consulting your owner's manual: This is the best resource for the exact location and instructions for draining your radiator.
* Searching online for a diagram: A quick image search for "[Your Buick Century Year] radiator drain plug location" will likely show you a picture.
Be careful when draining the radiator, as coolant is hot when the engine is warm and is corrosive. Use appropriate safety gear and a drain pan.