To find it, you'll need to:
1. Consult your owner's manual: It might have a diagram showing the location of the A/C components.
2. Look under the hood: Carefully inspect the A/C lines and components near the firewall. The accumulator/receiver-dryer is usually a cylindrical canister with various lines connected to it. The low-side service port will be a Schrader valve (similar to a tire valve) on this component. It is usually smaller than the high-side port.
3. Use a repair manual: A repair manual specific to your 1999 Buick Regal will provide detailed diagrams and instructions.
Important Note: Working with automotive refrigerant requires specialized equipment and knowledge. Improper handling of refrigerant can be dangerous. If you're not experienced with automotive A/C repair, it's best to take your vehicle to a qualified mechanic.