To be certain:
* Consult a repair manual specific to your 2002 Buick Century. This will provide diagrams and precise locations.
* Look carefully around the AC compressor. The low-side port is usually near the compressor's suction line. It will have a smaller fitting than the high-side port.
Caution: Working with refrigerant requires special equipment and knowledge. Improper handling can result in injury or damage to the system. If you are not experienced in automotive AC work, it is best to take your vehicle to a qualified mechanic.