Not directly. A Corvette wheel likely won't fit an S10 without significant modifications, if at all. The bolt patterns (number of lug nuts and their spacing), wheel offset, and center bore are almost certainly different between the two vehicles. Even if the bolt pattern *happened* to match (unlikely), the offset would probably be wrong, leading to rubbing issues, and the center bore might not fit the S10's hub.
You would need to verify all these dimensions (bolt pattern, offset, center bore, and wheel diameter/width) for both the Corvette wheel and your specific S10 model year to even consider the possibility, and even then, it's highly improbable. It's far safer and easier to buy wheels specifically designed for an S10.