Because your rear AC works fine, this strongly points to a problem with the front blend door actuator or its associated linkage, rather than a refrigerant or compressor issue. The actuator is a small motor that moves a door to mix hot and cold air. If it's stuck in the "heat" position, you'll only get hot air regardless of your settings.
Important Note: Accessing the blend door actuator requires some mechanical aptitude and familiarity with automotive repair. If you're not comfortable with this type of work, it's best to take your Expedition to a qualified mechanic. Improperly removing dashboard components can cause damage. A repair manual specific to your vehicle year and model would be extremely helpful in guiding you through the process.