It's usually a hex-head bolt or plug and often below the thermostat housing. You'll likely need to get under the truck to access it. It's a good idea to consult a repair manual specific to your year and model Silverado for a precise location and diagram. A Chilton's or Haynes manual would be helpful.
Important Note: Before draining coolant, be sure the engine is completely cool to prevent burns. Have a suitable container ready to catch the coolant. Also be aware that the coolant is likely to be toxic, so handle it appropriately.