To be certain, you should:
* Consult a repair manual: A Haynes or Chilton manual specific to your year and model will have a diagram showing the precise location.
* Use an online parts diagram: Many auto parts websites (like AutoZone, Advance Auto Parts, etc.) allow you to select your vehicle and view diagrams of its components.
* Search online for pictures: Searching for "1999 Chevy Express Vortec V6 EGR valve location" on Google Images might yield helpful pictures.
Remember, working on your engine can be dangerous. If you're not comfortable doing it yourself, it's best to take your van to a qualified mechanic.