To locate what you *think* might be cylinder #5 (for example, if you're looking at a diagram that uses that numbering), you'll need:
* A repair manual or engine diagram: These are crucial. They will show a detailed view of the engine, including the cylinder arrangement and firing order. You can often find these online (sometimes for purchase) or at an auto parts store.
* Understand the firing order: The firing order tells you the sequence in which the cylinders ignite. Once you know the order, you can trace it visually on the engine.
Without a specific diagram for your 2001 Lincoln Navigator's 5.4L engine, I cannot tell you the location of what you think is Cylinder 5. Using a repair manual is your best bet to avoid damage or confusion.